| Rank | Player | Country | Matches | 1st serve points won |
| 1 | S.Williams | USA | 5 | 131 of 165 = 79 % |
| 2 | R.Vinci | ITA | 3 | 100 of 133 = 75 % |
| 3 | L.Safarova | CZE | 2 | 71 of 95 = 75 % |
| 4 | M.Sharapova | RUS | 6 | 127 of 170 = 75 % |
| 5 | K.Flipkens | BEL | 4 | 87 of 118 = 74 % |
| 6 | K.Bertens | NED | 1 | 32 of 44 = 73 % |
| 7 | J.Cepelova | SVK | 2 | 62 of 86 = 72 % |
| 8 | M.Keys | USA | 3 | 66 of 92 = 72 % |
| 8 | V.Dushevina | RUS | 1 | 33 of 46 = 72 % |
| 10 | M.Lucic-Baroni | CRO | 1 | 30 of 42 = 71 % |
| 10 | J.Hampton | USA | 3 | 90 of 126 = 71 % |
| 12 | J.Goerges | GER | 4 | 117 of 165 = 71 % |
| 13 | A.Ivanovic | SRB | 4 | 107 of 152 = 70 % |
| 14 | Kr.Pliskova | CZE | 2 | 47 of 67 = 70 % |
| 15 | D.Vekic | CRO | 2 | 30 of 43 = 70 % |
| 16 | M.Erakovic | NZL | 1 | 58 of 84 = 69 % |
| 17 | V.Lepchenko | USA | 2 | 49 of 71 = 69 % |
| 18 | L.Robson | GBR | 3 | 102 of 148 = 69 % |
| 19 | S.Peng | CHN | 2 | 57 of 83 = 69 % |
| 20 | K.Mladenovic | FRA | 2 | 72 of 105 = 69 % |