| Women's Singles First Serve Points Won Leaders |
| Rank | Player | Country | Matches | First Serve Points Won |
| 1 | N.Vaidisova | CZE | 4 | 120 of 154 = 78% |
| 2 | S.Williams | USA | 5 | 135 of 175 = 77% |
| 3 | M.Sharapova | RUS | 7 | 165 of 214 = 77% |
| 4 | I.Tulyaganova | UZB | 1 | 22 of 29 = 76% |
| 5 | K.Srebotnik | SLO | 3 | 96 of 130 = 74% |
| 6 | L.Safarova | CZE | 1 | 20 of 28 = 71% |
| 6 | S.Dubois | CAN | 1 | 30 of 42 = 71% |
| 8 | A.Mauresmo | FRA | 3 | 116 of 164 = 71% |
| 9 | A.Molik | AUS | 2 | 62 of 88 = 70% |
| 10 | S.Kuznetsova | RUS | 3 | 69 of 98 = 70% |
| 11 | M.Kirilenko | RUS | 4 | 144 of 207 = 70% |
| 12 | A.Sugiyama | JPN | 3 | 74 of 107 = 69% |
| 13 | D.Hantuchova | SVK | 6 | 170 of 246 = 69% |
| 14 | P.Schnyder | SUI | 2 | 67 of 98 = 68% |
| 15 | A.Kleybanova | RUS | 2 | 66 of 97 = 68% |
| 16 | S.Mirza | IND | 3 | 87 of 128 = 68% |
| 17 | A.Ivanovic | SRB | 7 | 210 of 309 = 68% |
| 18 | J.Gajdosova | AUS | 1 | 19 of 28 = 68% |
| 19 | N.Petrova | RUS | 4 | 102 of 151 = 68% |
| 20 | A.Cornet | FRA | 2 | 54 of 80 = 68% |
