| Women's Singles First Serve Pct. Leaders |
| Rank | Player | Country | Matches | First Serve Pct. In |
| 1 | V.Ruano Pascual | ESP | 3 | 142 of 180 = 79% |
| 2 | M.Tu | USA | 1 | 74 of 94 = 79% |
| 3 | E.Dementieva | RUS | 4 | 181 of 233 = 78% |
| 4 | S.Ferguson | AUS | 1 | 44 of 57 = 77% |
| 5 | C.Pin | FRA | 2 | 108 of 142 = 76% |
| 6 | O.Govortsova | BLR | 1 | 27 of 36 = 75% |
| 6 | V.Zvonareva | RUS | 1 | 36 of 48 = 75% |
| 8 | A.Sugiyama | JPN | 3 | 107 of 143 = 75% |
| 9 | M.Yuan | CHN | 2 | 119 of 161 = 74% |
| 10 | L.Granville | USA | 1 | 38 of 52 = 73% |
| 11 | E.Loit | FRA | 1 | 46 of 63 = 73% |
| 12 | V.Azarenka | BLR | 3 | 118 of 163 = 72% |
| 13 | Y.Meusburger | AUT | 2 | 81 of 112 = 72% |
| 14 | E.Gallovits | ROU | 2 | 125 of 173 = 72% |
| 15 | A.Medina Garrigues | ESP | 2 | 106 of 147 = 72% |
| 16 | S.Arvidsson | SWE | 2 | 147 of 205 = 72% |
| 17 | M.Niculescu | ROU | 1 | 55 of 77 = 71% |
| 18 | A.Rodionova | AUS | 2 | 107 of 150 = 71% |
| 19 | A.Nakamura | JPN | 1 | 47 of 66 = 71% |
| 20 | E.Linetskaya | ISR | 1 | 42 of 59 = 71% |
